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The analysis of the optimized structures of the MichaelisMenten complex indicate that the polar residues at position 13 (Cys or Ser) stabilize the deprotonated GS , which in turn acts as the catalytic Brnsted base and abstracts the proton at position C2 of substrate 7 (Extended Data Fig

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Bellini, C., Mancin, F., Papini, E., & Tavano, R

Effect of testosterone supplementation with and without a dual 5-reductase inhibitor on fat-free mass in men with suppressed testosterone production: a randomized controlled trial