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Transcellular permeability Given the integrity of cellular structures and junctional proteins between ECs, it is typical for gases and small lipid-soluble molecules with molecular weights under 400 Da to be able to passively diffuse across the BBB [22]

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Furthermore, iron species, especially free iron ions, form specific iron-DA complexes and subsequently mediate extensive DA oxidation to produce deleterious DAQs and ROS, leading to proteasome inhibition, dopaminergic neuron vulnerability and degeneration [107]

1 Cryo-EM workflow of mTORC1-Rheb-Rag-Ragulator-4EBP1 on membrane