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This is the core challenge with both of these molecules

The presence of a catechol group in the B-ring, due to its ability to donate hydrogen, increases the formation of a relatively stable flavonoid-derived radical, which is the most important determinant of reactive oxygen and nitrogen species (RONS) inhibition (188)

J Biol Chem 286(30):2651626523 Gupta RK, Arany Z, Seale P, Mepani RJ, Ye L, Conroe HM, Spiegelman BM (2010) Transcriptional control of preadipocyte determination by Zfp423

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8.6 Patients with Hepatic Impairment Acetaminophen is contraindicated in patients with severe hepatic impairment or severe active liver disease and should be used with caution in patients with hepatic impairment or active liver disease [ see WARNINGS AND PRECAUTIONS (5.1) and CLINICAL PHARMACOLOGY (12)]